Silver bromide is used to coat ordinary black-and-white

Chapter 5, Problem 68P

(choose chapter or problem)

Get Unlimited Answers
QUESTION:

Silver bromide is used to coat ordinary black-and-white photographic film, while high-speed film uses silver iodide.

When \(50.0 mL\) of \(5.0 \mathrm{~g} / \mathrm{L} \ \mathrm{AgNO}_{3}\) is added to a coffee-cup calorimeter containing \(50.0 mL\) of \(5.0 g/L NaI\), with both solutions at \(25^{\circ} \mathrm{C}\), what mass of AgI forms?

Use Appendix B to find \(\Delta \mathrm{H}_{\mathrm{rxn}}^{\circ}\).

What is \(\Delta T_{\text {soln }}\) (assume the volumes are additive and the solution has the density and specific heat capacity of water)?

Equation Transcription:

5.0 g/L AgNO3

25°C

rxn

Tsoln

Text Transcription:

50.0 mL

5.0 g/L AgNO_3

5.0 g/L NaI

25°C

Delta H°_rxn

Delta T_soln

Questions & Answers

QUESTION:

Silver bromide is used to coat ordinary black-and-white photographic film, while high-speed film uses silver iodide.

When \(50.0 mL\) of \(5.0 \mathrm{~g} / \mathrm{L} \ \mathrm{AgNO}_{3}\) is added to a coffee-cup calorimeter containing \(50.0 mL\) of \(5.0 g/L NaI\), with both solutions at \(25^{\circ} \mathrm{C}\), what mass of AgI forms?

Use Appendix B to find \(\Delta \mathrm{H}_{\mathrm{rxn}}^{\circ}\).

What is \(\Delta T_{\text {soln }}\) (assume the volumes are additive and the solution has the density and specific heat capacity of water)?

Equation Transcription:

5.0 g/L AgNO3

25°C

rxn

Tsoln

Text Transcription:

50.0 mL

5.0 g/L AgNO_3

5.0 g/L NaI

25°C

Delta H°_rxn

Delta T_soln

ANSWER:

Problem 68P

Silver bromide is used to coat ordinary black-and-white photographic film, while high-speed film uses silver iodide.

(a) When 50.0 ml of 5.0 g/L  is added to a coffee-cup calorimeter containing 50.0 mL of 5.0 g/L NaI, with both solutions at 25  , what mass of AgI forms?

(b) Use Appendix B to find  .

(c) What is  (assume the volumes are additive and the solution has the density and specific heat capacity of water)?

                                                              Step by step solution

Step 1 of 3

(a) Balanced thermochemical equation for the reactants is given by

From the balanced chemical equation, one mole of  reacts with one mole of NaI to give one mole of AgI.

Molar mass of  = 169.91 g/mol

Mass of  = 0.05 L x 5.0 g/L

= 0.25 g

Number of moles of  

                                                     =  0.00147 moles

Molar mass of NaI = 149.9 g/mol

Mass of NaI = 0.05L x 5.0 g/L

                 = 0.25 g

Number of moles of  

                                 = 0.00166

  is the  limiting reagent.

1 mole of   forms one mole of AgI.

Then 0.00147 moles of  forms 0.00147 moles of AgI.

Molar mass of AgI = 234.8 g/ mol

Mass of AgI formed = 234.8 g/ mol x 0.00147 moles

                                 = 0.345 g

Add to cart


Study Tools You Might Need

Not The Solution You Need? Search for Your Answer Here:

×

Login

Login or Sign up for access to all of our study tools and educational content!

Forgot password?
Register Now

×

Register

Sign up for access to all content on our site!

Or login if you already have an account

×

Reset password

If you have an active account we’ll send you an e-mail for password recovery

Or login if you have your password back