A baker uses sodium hydrogen carbonate (baking soda) as

Chapter 6, Problem 70P

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QUESTION:

A baker uses sodium hydrogen carbonate (baking soda) as the leavening agent in a banana-nut quickbread. The baking soda decomposes according to two possible reactions:

(1) \(2 \mathrm{NaHCO}_{3}(s) \longrightarrow \mathrm{Na}_{2} \mathrm{CO}_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)\)

(2) \(\mathrm{NaHCO}_{3}(s)+\mathrm{H}^{+}(a q) \longrightarrow \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)+\mathrm{Na}^{+}(a q)\)

Calculate the volume (in mL) of \(\mathrm{CO}_{2}\) that forms at \(200^{\circ} \mathrm{C}\) and \(0.975 atm\) per gram of \(\mathrm{NaHCO}_{3}\) by each of the reaction processes.

Equation Transcription:

CO2

200°C

NaHCO3

Text Transcription:

2NaHCO_3(s) rightarrow Na_2CO_3(s) + H_2O(l)+CO_2(g)

NaHCO_3(s) + H^+(aq) rightarrow H_2O(l)+CO_2(g)+Na^+(aq)

CO_2

200°C

0.975 atm

NaHCO_3

Questions & Answers

QUESTION:

A baker uses sodium hydrogen carbonate (baking soda) as the leavening agent in a banana-nut quickbread. The baking soda decomposes according to two possible reactions:

(1) \(2 \mathrm{NaHCO}_{3}(s) \longrightarrow \mathrm{Na}_{2} \mathrm{CO}_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)\)

(2) \(\mathrm{NaHCO}_{3}(s)+\mathrm{H}^{+}(a q) \longrightarrow \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)+\mathrm{Na}^{+}(a q)\)

Calculate the volume (in mL) of \(\mathrm{CO}_{2}\) that forms at \(200^{\circ} \mathrm{C}\) and \(0.975 atm\) per gram of \(\mathrm{NaHCO}_{3}\) by each of the reaction processes.

Equation Transcription:

CO2

200°C

NaHCO3

Text Transcription:

2NaHCO_3(s) rightarrow Na_2CO_3(s) + H_2O(l)+CO_2(g)

NaHCO_3(s) + H^+(aq) rightarrow H_2O(l)+CO_2(g)+Na^+(aq)

CO_2

200°C

0.975 atm

NaHCO_3

ANSWER:

Solution 70P

Here, we have to calculate the moles of CO2 in two possible reactions of baking soda decomposition.

Step 1 of 2

The baking soda decomposes into two possible reactions.

  1. 2NaHCO3(s)   Na2CO3(s)  + H2O(l) + CO2(g)

First, let’s calculate the number of moles of NaHCO3 in 1g of Baking Soda.

Number of mole of NaHCO3 = 

                                              = 

                                              = 0.0119 mol

Therefore, moles of NaHCO3 is 0.0119 mol.

Let’s calculate the number of moles of CO2 Produced.

From the given chemical equation

2 moles of  NaHCO3  produce 1 mole of CO2

Mole- mole factor is 

   = 0.0119 mol NaHCO3 

  = 0.00595 mol of CO2.

Therefore, moles of CO2 is 0.00595 mol.

Let’s calculate the volume of CO2 gas.

Write the Ideal gas equation

PV = nRT

Rearrange the formula is as follows.

V =

Given

n= 0.00595 mol

R = 0.821 L.atm.mol-1.K-1.

T = 473 k

P = 0.975 atm.

 Substitute the values.

=

= 0.237 L

Therefore, volume of CO2 is 0.237 L.

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