Which has the smaller ?Hhydr in each pair of 13.33?

Chapter 14, Problem 23P

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QUESTION:

Problem 23P

Which has the smaller ΔHhydr in each pair of Problem 13.33?

Questions & Answers

QUESTION:

Problem 23P

Which has the smaller ΔHhydr in each pair of Problem 13.33?

ANSWER:

Solution 23P

Here, we are going to find out the ion or molecule which have larger hydration enthalpy among each pair.

Step 1:

We know that,

Heat of hydration() is directly proportional to the charge density of the ion.

Where,

Charge density is defined as the ratio of the charge of ions to the volume of the ions.

Thus, it is dependent on the properties of ion as

  1. Charge on the ion.
  2. Volume of the ions.

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