When a glass bottle full of vinegar warms up, both the vinegar and the glass expand, but

Chapter 5, Problem 16

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When a glass bottle full of vinegar warms up, both the vinegar and the glass expand, but vinegar expands significantly more with temperature than glass. The bottle will break if it was filled to its tightly capped lid. Explain why, and also explain how a pocket of air above the vinegar would prevent the break. (This is the function of the air above liquids in glass containers.)

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