Phosphorus trichloride gas and chlorine gas react to form

Chapter , Problem 15.34

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Phosphorus trichloride gas and chlorine gas react to form phosphorus pentachloride gas: PCl31g2 + Cl21g2 PCl51g2. A 7.5-L gas vessel is charged with a mixture of PCl31g2 and Cl21g2, which is allowed to equilibrate at 450 K. At equilibrium the partial pressures of the three gases are PPCl3 = 0.124 atm, PCl2 = 0.157 atm, and PPCl5 = 1.30 atm. (a) What is the value of Kp at this temperature? (b) Does the equilibrium favor reactants or products? (c) Calculate Kc for this reaction at 450 K.

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