Chemistry 7th Edition - Solutions by Chapter

A compound that reacts with a diene in a Diels-Alder reaction.

In electrocyclicreactions, a type of rotation in which the orbitalsbeing used to form the new s bond must rotate in opposite directions (one rotates clockwise while the other rotates counterclockwise).

A reaction that occurs between chlorobenzene and either NaOH (at high temperature) or NaNH2.

A vacancy in the valence band of a semiconductor, created by doping. (Section 12.7)

Thedetermining factor by which ions are separatedfrom each other in mass spectrometry.

A combination of two or more substances in which each substance retains its own chemical identity. (Section 1.2)

A reaction in which a nucleophile attacks a carboxylic acid derivative.

An allowed energy state of an electron in the quantum mechanical model of the atom; the term orbital is also used to describe the spatial distribution of the electron. An orbital is defined by the values of three quantum numbers: n, l, and ml (Section 6.5)

Units used on NMR spectra to record chemical shift relative to the TMS standard.

A rule stating that no two electrons in an atom may have the same four quantum numbers (n, l, ml, and ms). As a reflection of this principle, there can be no more than two electrons in any one atomic orbital. (Section 6.7)

A conformation in which a hydrogen atom and a leaving group are approximately coplanar.

A plane that bisects a compound into two halves that are mirror images of each other.

A polymer that can be molded when hot and retains its shape when cooled

The determination of the amount of a given substance that is present in a sample. (Section 17.7)

The gain of electrons. Alternatively, either the gain of hydrogen, loss of oxygen, or both

The difference in energy between a resonance hybrid and the most stable of its hypothetical contributing structures in which electrons are localized on particular atoms and in particular bonds.

An amine in which nitrogen is bonded to two carbons and one hydrogen

The preferred metric units for use in science. (Section 1.4)

A homogeneous alloy, where two or more elements are distributed randomly and uniformly throughout the solid. (Section 12.3)

Constitutional isomers in equilibrium with each other that differ in the location of a hydrogen atom and a double bond relative to a heteroatom, most commonly O, N, or S.