- 6.6.12: a. What is the major product of each of the following reactions? 1....
- 6.6.13: How could the following compound be prepared, using an alkene as on...
- 6.6.14: How could the following compounds be prepared, using an alkene as o...
- 6.6.15: Propose a mechanism for the following reaction (remember to use cur...
Solutions for Chapter 6.6: The Addition of an Alcohol to an Alkene
Full solutions for Organic Chemistry | 7th Edition
The slow oxidation of organic compounds that occurs in the presence of atmospheric oxygen.
A law stating that at constant temperature, the product of the volume and pressure of a given amount of gas is a constant. (Section 10.3)
A substance formed by addition of a proton to a Brønsted–Lowry base. (Section 16.2)
A neutral species containing one or more complex ions. (23.3)
crystal field splitting (D).
The energy difference between two sets of d orbitals in a metal atom when ligands are present. (23.5)
The angle created by two intersecting planes.
Intermolecular forces resulting from attractions between induced dipoles. Also called London dispersion forces. (Section 11.2)
A material that can undergo a substantial change in shape via stretching, bending, or compression and return to its original shape upon release of the distorting force. (Section 12.6)
A diagram that shows the energies of molecular orbitals relative to the atomic orbitals from which they are derived. Also called a molecular-orbital diagram. (Section 9.7)
A reaction in which the enthalpy of the products is lower than that of the reactants; a reaction in which heat is released.
A molecule containing an !OH and an !OR or !OAr group bonded to the same carbon
A property that is independent of the amount of material considered, for example, density. (Section 1.3)
A group capable ofseparating from a compound.
A reaction in which a nucleophile attacks a conjugated p system, resulting in a 1,4-addition.
The common name for bicyclo[2.2.1]heptane.
nucleophilic aromatic substitution
A substitution reaction in which an aromatic ring is attacked by a nucleophile, which replaces a leaving group.
polar aprotic solvent
A solvent that lacks hydrogen atoms connected directly to an electronegative atom.
Polar covalent bond
A covalent bond between atoms whose difference in electronegativity is between approximately 0.5 and 1.9.
Quaternary (4°) ammonium ion
An ion in which nitrogen is bonded to four carbons and bears a positive charge
A reaction that converts an aldehyde or ketone into an alkene, with the introduction of one or more carbon atoms.