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Solutions for Chapter 6.18: Reactions and Synthesis

Organic Chemistry | 7th Edition | ISBN: 9780321803221 | Authors: Paula Yurkanis Bruice

Full solutions for Organic Chemistry | 7th Edition

ISBN: 9780321803221

Organic Chemistry | 7th Edition | ISBN: 9780321803221 | Authors: Paula Yurkanis Bruice

Solutions for Chapter 6.18: Reactions and Synthesis

Since 3 problems in chapter 6.18: Reactions and Synthesis have been answered, more than 38243 students have viewed full step-by-step solutions from this chapter. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 7. This expansive textbook survival guide covers the following chapters and their solutions. Organic Chemistry was written by and is associated to the ISBN: 9780321803221. Chapter 6.18: Reactions and Synthesis includes 3 full step-by-step solutions.

Key Chemistry Terms and definitions covered in this textbook
  • Activating group

    Any substituent on a benzene ring that causes the rate of electrophilic aromatic substitution to be greater than that for benzene.

  • band gap

    The energy gap between a fully occupied band called a valence band and an empty band called the conduction band. (Section 12.7)

  • bond-line structures

    The most common drawing style employed by organic chemists. All carbon atoms and most hydrogen atoms are implied but not explicitly drawn in a bond-line structure.

  • capillary action

    The process by which a liquid rises in a tube because of a combination of adhesion to the walls of the tube and cohesion between liquid particles. (Section 11.3)

  • cathodic protection

    A means of protecting a metal against corrosion by making it the cathode in a voltaic cell. This can be achieved by attaching a more easily oxidized metal, which serves as an anode, to the metal to be protected. (Section 20.8)

  • conductor.

    Substance capable of conducting electric current. (21.3)

  • Cyanohydrin

    A molecule containing an !OH group and a !CN group bonded to the same carbon.

  • Dispersion forces

    Very weak intermolecular forces of attraction resulting from the interaction between temporary induced dipoles

  • exo

    In Diels-Alder reactions that produce bicyclic structures, the positions that are anti to the larger bridge.

  • Heterolytic bond cleavage

    Cleavage of a bond so that one fragment retains both electrons and the other retains none.

  • mixture

    A combination of two or more substances in which each substance retains its own chemical identity. (Section 1.2)

  • molal freezing-point-depression constant (Kf)

    A constant characteristic of a particular solvent that gives the decrease in freezing point as a function of solution molality: ?Tf = -Kf m. (Section 13.5)

  • phenolate

    The conjugate base of phenol or a substituted phenol.

  • polypeptide

    A polymer of amino acids that has a molecular weight of less than 10,000. (Section 24.7)

  • primary structure

    For proteins, the sequence of amino acid residues.

  • property

    A characteristic that gives a sample of matter its unique identity. (Section 1.1)

  • shielded

    In NMR spectroscopy,protons or carbon atoms whose surrounding electron density is rich.

  • SN1

    A unimolecular nucleophilic substitution reaction.

  • solvolysis

    A substitution reaction in which the solvent functions as the nucleophile.

  • Stereocenter

    An atom, most commonly carbon, about which exchange of two groups produces a stereoisomer. Chiral centers are one type of stereocenter

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