- 13.9.16: a. How many stereoisomers are formed from the reaction of cyclohexe...
- 13.9.17: Two products are formed when methylenecyclohexane reacts with NBS. ...
- 13.9.18: How many allylic substituted bromoalkenes are formed from the react...
- 13.9.19: How many allylic substituted bromoalkenes are formed from the react...
- 13.9.20: Draw the resonance contributors for the following radicals:
- 13.9.21: a. Draw the major product(s) of the reaction of 1-methylcyclohexene...
Solutions for Chapter 13.9: Radical Substitution of Benzylic and Allylic Hydrogens
Full solutions for Organic Chemistry | 7th Edition
Solutions for Chapter 13.9: Radical Substitution of Benzylic and Allylic HydrogensGet Full Solutions
A conformation in which a hydrogen atom and a leaving group are separated by a dihedral angle of exactly 180°.
beta (b) pleated sheet
For proteins, a feature of secondary structure that forms when two or more protein chains line up side-by-side.
A strong attractive force that exists between atoms in a molecule. (Section 8.1)
A plant pigment that plays a major role in conversion of solar energy to chemical energy in photosynthesis. (Section 23.3)
A compound that reacts with a diene in a Diels-Alder reaction.
energy of activation
In an energy diagram, the height of the energy barrier (the hump) between the reactants and the products.
A barbed curved arrow used to show the change in position of a single electron.
In mass spectrometry, when the molecular ion breaks apart into fragments.
Energetic electromagnetic radiation emanating from the nucleus of a radioactive atom. (Section 21.1)
hydronium ion 1H3O+2
The predominant form of the proton in aqueous solution. (Section 16.2)
For water, Kw is the product of the aquated hydrogen ion and hydroxide ion concentrations: 3H+43OH-4 = Kw = 1.0 * 10-14 at 25 °C. (Section 16.3)
Le Châtelier’s principle
A principle stating that when we disturb a system at chemical equilibrium, the relative concentrations of reactants and
An equation that relates the cell emf, E, to the standard emf, E°, and the reaction quotient, Q: E = E° - 1RT>nF2 ln Q. (Section 20.6)
A compound that lacks a ring with a continuous system of overlapping p orbitals.
The pressure that must be applied to a solution to stop osmosis from pure solvent into the solution. (Section 13.5)
pi 1P2 molecular orbital
A molecular orbital that concentrates the electron density on opposite sides of an imaginary line that passes through the nuclei. (Section 9.8)
Polymers made up of repeating urethane groups, also sometimes called carbamate groups (!N!CO2!).
A theory that many molecules and ions are best described as a hybrid of several Lewis structures
A reaction in which one substrate produces two stereoisomers in unequal amounts.
A compound containing an !SH (sulfhydryl) group bonded to an sp3 -hybridized carbon.