- 15.22.44: Identify pairs of coupled protons in the compound whose COSY spectr...
- 15.22.45: Identify pairs of coupled protons in the compound whose COSY spectr...
Solutions for Chapter 15.22: Two-Dimensional NMR Spectroscopy
Full solutions for Organic Chemistry | 7th Edition
A format for naming amines containing simple alkyl groups.
A negatively charged ion. (Section 2.7)
A polymerization that involves sequential addition reactions, either to unsaturated monomers or to monomers possessing other reactive functional groups.
Dalton’s law of partial pressures.
The total pressure of a mixture of gases is just the sum of the pressures that each gas would exert if it were present alone. (5.6)
An unsaturated compound derived by the reaction of an aldehyde or ketone and a secondary amine followed by loss of H2O; R2C"CR!NR2
The ability to do work.
First ionization potential
The energy needed to remove the most loosely held electron from an atom or molecule.
A substance with one or more unpaired electrons. (Section 21.9)
For electromagnetic radiation, the number of wavelengths that pass a particular point in space per unit time.
A carbanion with the structure RMgX.
The mixing of different types of atomic orbitals to produce a set of equivalent hybrid orbitals. (Section 9.5)
A nonpolar group that does not have favorable interactions with water.
Infrared (IR) spectroscopy
A spectroscopic technique in which a compound is irradiated with infrared radiation, absorption of which causes covalent bonds to change from a lower vibration state to a higher one. Infrared spectroscopy is particularly valuable for determining the kinds of functional groups present in a molecule.
A compound with the structure R!C#C!R, where each R group is not a hydrogen atom.
The concentration of a solution expressed as moles of solute per liter of solution; abbreviated M. (Section 4.5)
An equation that relates the reaction rate to the concentrations of reactants (and sometimes of products also). (Section 14.3)
Separation of a racemic mixture into its enantiomers; in mass spectrometry, a measure of how well a mass spectrometer separates ions of different mass.
Ions that go through a reaction unchanged and that appear on both sides of the complete ionic equation. (Section 4.2)
The right side of an NMRspectrum.
A double-helix model for the secondary structure of a DNA molecule