Organic Chemistry 2nd Edition - Solutions by Chapter

If a hydrogen has n hydrogens nonequivalent to it but equivalent among themselves on the same or adjacent atom(s), its 1 H!NMR signal is split into (n 1 1) peaks

For proteins, a feature of secondary structure that forms when a portion of the protein twists into a spiral.

A mass exactly equal to 1 12th the mass of one carbon-12 atom. (3.1)

A cholesterol-derived detergent molecule, such as cholic acid, which is secreted by the gallbladder into the intestine to assist in the absorption of dietary lipids.

A measure of the polarity of a covalent bond. The product of the charge on either atom of a polar bond times the distance between the atoms

A form of carbon produced when wood is heated strongly in a deficiency of air. (Section 22.9)

A liquid crystal formed from flat, disc-shaped molecules that align through a stacking of the molecular discs. (Section 11.7)

The absence of two hydrogen atoms associated with a ring or a p bond.

A molecule containing two amino acid units joined by a peptide bond

Lanthanide and actinide elements in which the 4f or 5f orbitals are partially occupied. (Section 6.9)

Spin-spin coupling that occurs between nonequivalent H atoms bonded to the same C atom. The H atoms are generally nonequivalent owing to restricted bond rotation in the molecule

Plasma particles, density 1.06–1.21 g/mL, consisting of approximately 33% proteins, 30% cholesterol, 29% phospholipids, and 8% triglycerides.

A twostep process that achieves an anti-Markovnikov addition of a proton and a hydroxyl group (OH) across an alkene.

A six-membered cyclic form of a monosaccharide.

A detailed picture, or model, of how the reaction occurs; that is, the order in which bonds are broken and formed and the changes in relative positions of the atoms as the reaction proceeds. (Section 14.6)

A theory that many molecules and ions are best described as a hybrid of several Lewis structures

The reverse of an aldol reaction. A b-hydroxyketone or aldehyde is converted into two ketones or aldehydes.

The conversion of an aryl diazonium salt into fluorobenzene upon treatment with fluoroboric acid (HBF4).

A compound whose carbon skeleton can be divided into two or more units identical with the carbon skeleton of isoprene

A solution to a set of equations that defi nes the energy of an electron in an atom and the region of space it may occupy.