As you demonstrated in .18, fl uorination of alkanes is

Chapter 8, Problem 8.19

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As you demonstrated in 8.18, fl uorination of alkanes is highly exothermic. As per Hammonds postulate, assume that the transition state for radical fl uorination is almost identical to the starting material. With this assumption, estimate the fraction of each monofl uoro product formed in the fl uorination of 2-methylbutane

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