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Propose a structural formula for the cation at m/z 41 observed in the massspectrum of

Organic Chemistry | 7th Edition | ISBN: 9781133952848 | Authors: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote ISBN: 9781133952848 483

Solution for problem 14.2 Chapter 14

Organic Chemistry | 7th Edition

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Organic Chemistry | 7th Edition | ISBN: 9781133952848 | Authors: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Organic Chemistry | 7th Edition

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Problem 14.2

Propose a structural formula for the cation at m/z 41 observed in the massspectrum of methylcyclopentane.

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Ligands o Monodentate  Only coordinates to the metal at one spot on molecule o Bidentate & Polydentate  Can coordinate to the metal at multiple spots  Typically larger molecules  i.e. Ethylenediamine (en) below  Formation Constants o Complex with larger formation constant forms more favorably o K fiffer because of Gibbs Free Energy  Chelate Effect (kee-late)  Larger K fave larger change in entropy  Chelating Agents o Remove or separate metal ions from a solution o i.e. EDTA removes poisonous trace metals in food  Energy in Coordinate Chemistry o Ligand’s electrons are attracted to metal cation  Increases energy of the d-orbitals o Crystal Field Splitting  Difference in energy among d-orbitals based on ligand geometry  Used to explain many observations about coordinate chemistry, such as color and magnetism  Octohedral Geometry  Ligands are along x, y, z axes  Raises energy of d z2and d x -yorbitals the most  Raises energy of other d orbitals less  Tetrahedral Geometry  Ligands come between axes 2 2 2  Raises energy of d z and d x -y orbitals less  Raises energy of other d orbitals th

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Chapter 14, Problem 14.2 is Solved
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Textbook: Organic Chemistry
Edition: 7
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
ISBN: 9781133952848

This full solution covers the following key subjects: . This expansive textbook survival guide covers 24 chapters, and 1131 solutions. Since the solution to 14.2 from 14 chapter was answered, more than 347 students have viewed the full step-by-step answer. The full step-by-step solution to problem: 14.2 from chapter: 14 was answered by , our top Chemistry solution expert on 03/16/18, 05:02PM. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 7. The answer to “Propose a structural formula for the cation at m/z 41 observed in the massspectrum of methylcyclopentane.” is broken down into a number of easy to follow steps, and 16 words. Organic Chemistry was written by and is associated to the ISBN: 9781133952848.

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Propose a structural formula for the cation at m/z 41 observed in the massspectrum of