When the Pd(0)-catalyzed reactions covered in this chapter are run with a slightpressure

Chapter 24, Problem 24.27

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When the Pd(0)-catalyzed reactions covered in this chapter are run with a slightpressure of carbon monoxide, a ketone is often created as the product. Forexample, the following Stille coupling conditions with added CO give the productshown. Write a mechanism for how this reaction could occur using the organo-metallic mechanistic steps introduced in this chapter, along with new steps thatwould be required in this transformation. Hint: CO can coordinate to Pd andinsert into Pd-C bonds.

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