The mass spectra of acid derivatives follow the principles shown in Chapter 18 for other

Chapter 0, Problem 21-63

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The mass spectra of acid derivatives follow the principles shown in Chapter 18 for other carbonyl compounds and for alkoxy groups. Both McLafferty rearrangements and alpha-cleavages are common. The mass spectrum for butyl butanoate shows two prominent even-mass fragments at m z 88 and m z 60. Propose structures for these two fragments, and show what fragmentations produce them.

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