Another useful aspect of Pd(0)-catalyzed allylic

Chapter 24, Problem 24.22

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Another useful aspect of Pd(0)-catalyzed allylic alkylation is the ability to take reactants that are meso and desymmetrize them in the resulting products through the addition of a chiral ligand for the Pd metal. Draw the two h3 -allylic complexes formed in this reaction of the following reactant with PdL4. Describe why chirality in a ligand L would infl uence the preference for one of these complexes over the other. AcO OAc

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