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Dimethylamine, has a molecular weight of 45 and a boiling

Chapter 2, Problem 6P

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QUESTION:

Dimethylamine, \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}\), has a molecular weight of 45 and a boiling point of \(7.4^{\circ} C\) Trimethylamine, \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\), has a higher molecular weight (59) but a lower boiling point \(\left(3.5^{\circ} \mathrm{C}\right)\). Explain this apparent discrepancy.

Equation Transcription:

Text Transcription:

(CH3) 2NH

7.4°C

(CH3) 3N

(3.5°C)

Questions & Answers

QUESTION:

Dimethylamine, \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}\), has a molecular weight of 45 and a boiling point of \(7.4^{\circ} C\) Trimethylamine, \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\), has a higher molecular weight (59) but a lower boiling point \(\left(3.5^{\circ} \mathrm{C}\right)\). Explain this apparent discrepancy.

Equation Transcription:

Text Transcription:

(CH3) 2NH

7.4°C

(CH3) 3N

(3.5°C)

ANSWER:

Solution 6P

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