Answer: Precipitation and Separation of Ions (Section)A

Chapter 10, Problem 73E

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Problem 73E

Precipitation and Separation of Ions (Section)

A solution contains three anions with the following concentrations:

0.20 M CrO42–, 0.10 M CO32–, and 0.010 M Cl–. If a dilute AgNO3 solution is slowly added to the solution, what is the first compound to precipitate: Ag2CrO4 (Ksp = 1.2 × 10–12), Ag2CO3(Ksp = 8.1 × 10–12), or AgCl (Ksp = 1.8 × 10–10)?

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