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Chapter 14, Problem 51P

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QUESTION:

Problem 51P

How could IR spectroscopy distinguish between 1,5-hexadiene and 2,4-hexadiene?

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QUESTION:

Problem 51P

How could IR spectroscopy distinguish between 1,5-hexadiene and 2,4-hexadiene?

ANSWER:

Solution  51P

The IR absorption values of the alkenes are as follows:

Mono substituted alkenes (terminal alkenes) show three IR absorptions.

The stretching shows a medium absorption at.

The stretching shows a medium absorption at.

The  out of plane bending shows a strong absorption at.

Di substituted alkenes (internal alkenes) show three IR absorptions.

The stretching shows week absorption at.

The stretching shows week absorption at .

The

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