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A 19.2-g quantity of dry ice (solid carbon (dioxide) is

Chapter 6, Problem 107P

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QUESTION:

A 19.2-g quantity of dry ice (solid carbon dioxide) is allowed to sublime (evaporate) in an apparatus like the one shown in Figure 6.5. Calculate the expansion work done against a constant external pressure of 0.995 atm and at a constant temperature of \(22^{\circ} \mathrm{C}\). Assume that the initial volume of dry ice is negligible and that \(\mathrm{CO}_{2}\) behaves like an ideal gas.

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QUESTION:

A 19.2-g quantity of dry ice (solid carbon dioxide) is allowed to sublime (evaporate) in an apparatus like the one shown in Figure 6.5. Calculate the expansion work done against a constant external pressure of 0.995 atm and at a constant temperature of \(22^{\circ} \mathrm{C}\). Assume that the initial volume of dry ice is negligible and that \(\mathrm{CO}_{2}\) behaves like an ideal gas.

ANSWER:

Step 1 of 2

Here we have to calculate the expansion of work done against a constant external pressure 0.995 atm and at a constant temperature of 22°C.

 

Given:

Mass of dry ice () = 19.2 g

Molecular mass of  = 44.01 g

Number of moles of  (n) = 19.2 g / 44.01g/mol = 0.436 moles

Pressure = 0.995 atm

Temperature = 22 °C + 273 = 295 K

 

It is known that work done can be calculated as,

 

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