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At 25°C, the standard enthalpy of formation of HF(aq) is

Chapter 6, Problem 118P

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QUESTION:

At \(25^{\circ} \mathrm{C}\), the standard enthalpy of formation of HF(aq) is given by - 320.1 kJ/mol; of \(O H^{-}(a q)\), it is -229.6 kJ/mol; of \(F^{-}(a q)\), it is - 329.1 kJ/mol; and of \(\mathrm{H}_{2} \mathrm{O}(\mathrm{l})\), it is -285.8 kJ/mol.

(a) Calculate the standard enthalpy of neutralization of HF(aq):

\(H F(a q)+O H^{-}(a q) \rightarrow H_{2} O(l)\)

(b) Using the value of -56.2 kJ as the standard enthalpy change for the reaction

\(H^{+}(a q)+O H^{-}(a q) \rightarrow H_{2} O(l)\)

calculate the standard enthalpy change for the reaction

\(H F(a q) \rightarrow H^{+}(a q)+F^{-}(a q)\)

Questions & Answers

QUESTION:

At \(25^{\circ} \mathrm{C}\), the standard enthalpy of formation of HF(aq) is given by - 320.1 kJ/mol; of \(O H^{-}(a q)\), it is -229.6 kJ/mol; of \(F^{-}(a q)\), it is - 329.1 kJ/mol; and of \(\mathrm{H}_{2} \mathrm{O}(\mathrm{l})\), it is -285.8 kJ/mol.

(a) Calculate the standard enthalpy of neutralization of HF(aq):

\(H F(a q)+O H^{-}(a q) \rightarrow H_{2} O(l)\)

(b) Using the value of -56.2 kJ as the standard enthalpy change for the reaction

\(H^{+}(a q)+O H^{-}(a q) \rightarrow H_{2} O(l)\)

calculate the standard enthalpy change for the reaction

\(H F(a q) \rightarrow H^{+}(a q)+F^{-}(a q)\)

ANSWER:

Step 1 of 3

(a) Here we have to calculate the standard enthalpy of neutralization of HF(aq) ().

Given:

The given chemical reaction is ,

 

Temperature = 25 °C

 Enthalpy of formation of HF = -320.1 KJ/mol

Enthalpy of formation of  = -229.6 KJ/mol

Enthalpy of formation of  = -329.1 KJ/mol

Enthalpy of formation of water = -285.8 KJ/mol

 

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