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Although nitrogen dioxide (N02) is a stable com­pound,

Chapter 9, Problem 117P

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QUESTION:

Although nitrogen dioxide \(\left(\mathrm{NO}_{2}\right)\) is a stable compound, there is a tendency for two such molecules to combine to form dinitrogen tetroxide \(\left(\mathrm{N}_{2} \mathrm{O}_{4}\right)\). Why? Draw four resonance structures of \(\mathrm{N}_{2} \mathrm{O}_{4}\), showing formal charges.

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QUESTION:

Although nitrogen dioxide \(\left(\mathrm{NO}_{2}\right)\) is a stable compound, there is a tendency for two such molecules to combine to form dinitrogen tetroxide \(\left(\mathrm{N}_{2} \mathrm{O}_{4}\right)\). Why? Draw four resonance structures of \(\mathrm{N}_{2} \mathrm{O}_{4}\), showing formal charges.

ANSWER:

Step 1 of 3

Here, we draw a resonance structures for the Dinitrogen tetraoxide.

Dinitrogen tetroxide:

Two  molecules are combined to form .

Due to paramagnetic nature of the  molecules are combine together to form dimer ().

Structure of  is given below.

       

   

     

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