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(a) From the following data calculate the bond en­thalpy

Chapter 9, Problem 110P

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QUESTION:

(a) From the following data calculate the bond enthalpy of the \(\mathrm{F}_{2}^{-}\) ion.

\(\mathrm{F}_2(g)\longrightarrow2\mathrm{F}(g)\quad\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \Delta H_{\mathrm{rxn}}^{\circ}=156.9\mathrm{\ kJ}/\mathrm{mol}\)

\(\mathrm{F}^-(g)\longrightarrow\mathrm{F}(g)+e^-\quad\ \ \ \ \ \ \ \ \ \Delta H_{\mathrm{rxn}}^{\circ}=333\mathrm{\ kJ}/\mathrm{mol}\)

\(\mathrm{F}_2^-(g)\longrightarrow\mathrm{F}_2(g)+e^-\ \ \ \ \ \ \ \quad\Delta H_{\mathrm{rxn}}^{\circ}=290\mathrm{\ kJ}/\mathrm{mol}\)

(b) Explain the difference between the bond enthalpies of \(\mathrm{F}_{2}\) and \(\mathrm{F}_{2}^{-}\).

Questions & Answers

QUESTION:

(a) From the following data calculate the bond enthalpy of the \(\mathrm{F}_{2}^{-}\) ion.

\(\mathrm{F}_2(g)\longrightarrow2\mathrm{F}(g)\quad\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \Delta H_{\mathrm{rxn}}^{\circ}=156.9\mathrm{\ kJ}/\mathrm{mol}\)

\(\mathrm{F}^-(g)\longrightarrow\mathrm{F}(g)+e^-\quad\ \ \ \ \ \ \ \ \ \Delta H_{\mathrm{rxn}}^{\circ}=333\mathrm{\ kJ}/\mathrm{mol}\)

\(\mathrm{F}_2^-(g)\longrightarrow\mathrm{F}_2(g)+e^-\ \ \ \ \ \ \ \quad\Delta H_{\mathrm{rxn}}^{\circ}=290\mathrm{\ kJ}/\mathrm{mol}\)

(b) Explain the difference between the bond enthalpies of \(\mathrm{F}_{2}\) and \(\mathrm{F}_{2}^{-}\).

ANSWER:

Step 1 of 3

According to Hess law, the overall enthalpy change of a reaction is equal to the sum of the enthalpy changes involving in each and every individual steps in the reaction.

                                     

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