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Given the same reactant concentrations, the reactionCO(g)

Chapter 13, Problem 38P

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QUESTION:

Given the same reactant concentrations, the reaction

                \(\mathrm{CO}(\mathrm{g})+\mathrm{Cl}_2(\mathrm{~g}) \longrightarrow \mathrm{COCl}_2(\mathrm{~g})\)

at \(250^{\circ} \mathrm{C}\) is \(1.50 \times 10^3\) times as fast as the same reaction at \(150^{\circ} \mathrm{C}\). Calculate the activation energy for this reaction. Assume that the frequency factor is constant.

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QUESTION:

Given the same reactant concentrations, the reaction

                \(\mathrm{CO}(\mathrm{g})+\mathrm{Cl}_2(\mathrm{~g}) \longrightarrow \mathrm{COCl}_2(\mathrm{~g})\)

at \(250^{\circ} \mathrm{C}\) is \(1.50 \times 10^3\) times as fast as the same reaction at \(150^{\circ} \mathrm{C}\). Calculate the activation energy for this reaction. Assume that the frequency factor is constant.

ANSWER:

Step 1 of 3

Given that the reaction is  faster at  than at .

The Arrhenius equation can be written as follows.

                                                   

Where k is the rate constant, A is the Arrhenius constant, E is the activation energy, R is the universal gas constant, T is the temperature.

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