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Chapter 14, Problem 8P

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QUESTION:

Write equilibrium constant expressions for \(K_{C}\), and for \(K_{P}\), if applicable, for the following processes:

(a) \(K_{P}2 \mathrm{CO}_{2}(g)\ \leftrightharpoons\ 2 \mathrm{CO}(g)+\mathrm{O}_{2}(g)\)

(b) \(3 \mathrm{O}_{2}(\mathrm{g})\ \leftrightharpoons\ 2 \mathrm{O}_{3}(g)\)

(c) \(\mathrm{CO}(g)+\mathrm{Cl}_{2}(g)\ \leftrightharpoons\ \mathrm{COCl}_{2}(g)\)

(d) \(\mathrm{H}_{2} \mathrm{O}(g)+C(s)\ \leftrightharpoons\ C O(g)+\mathrm{H}_{2}(g)\)

(e) \(\mathrm{HCOOH}(a q)\ \leftrightharpoons\ \mathrm{H}^{+}(a q)+\mathrm{HCOO}^{-}(a q)\)

(f) \(2 \mathrm{HgO}(\mathrm{s})\ \leftrightharpoons\ 2 \mathrm{Hg}(\mathrm{l})+\mathrm{O}_{2}(g)\)

Questions & Answers

QUESTION:

Write equilibrium constant expressions for \(K_{C}\), and for \(K_{P}\), if applicable, for the following processes:

(a) \(K_{P}2 \mathrm{CO}_{2}(g)\ \leftrightharpoons\ 2 \mathrm{CO}(g)+\mathrm{O}_{2}(g)\)

(b) \(3 \mathrm{O}_{2}(\mathrm{g})\ \leftrightharpoons\ 2 \mathrm{O}_{3}(g)\)

(c) \(\mathrm{CO}(g)+\mathrm{Cl}_{2}(g)\ \leftrightharpoons\ \mathrm{COCl}_{2}(g)\)

(d) \(\mathrm{H}_{2} \mathrm{O}(g)+C(s)\ \leftrightharpoons\ C O(g)+\mathrm{H}_{2}(g)\)

(e) \(\mathrm{HCOOH}(a q)\ \leftrightharpoons\ \mathrm{H}^{+}(a q)+\mathrm{HCOO}^{-}(a q)\)

(f) \(2 \mathrm{HgO}(\mathrm{s})\ \leftrightharpoons\ 2 \mathrm{Hg}(\mathrm{l})+\mathrm{O}_{2}(g)\)

ANSWER:

Step 1 of 7

(a)

The given reaction is as follows;

                                               

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