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Chapter 14, Problem 29P

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QUESTION:

The following equilibrium constants have been determined for hydrosulfuric acid at \(25^{\circ} \mathrm{C}\):

\(H_{2} S(a q)\ \leftrightharpoons\ H^{+}(a q)+H S^{-}(a q)\)

                                                \(K_{c}^{\prime}=9.5 \times 10^{-8}\)

\(H S^{-}(a q)\ \leftrightharpoons\ H^{+}(a q)+S^{2-}(a q)\)

                                              \(K_{c}^{\prime \prime}=1.0 \times 10^{-19}\)

Calculate the equilibrium constant for the following reaction at the same temperature:

\(H_{2} S(a q)\ \leftrightharpoons\ 2 H^{+}(a q)+S^{2-}(a q)\)

Questions & Answers

QUESTION:

The following equilibrium constants have been determined for hydrosulfuric acid at \(25^{\circ} \mathrm{C}\):

\(H_{2} S(a q)\ \leftrightharpoons\ H^{+}(a q)+H S^{-}(a q)\)

                                                \(K_{c}^{\prime}=9.5 \times 10^{-8}\)

\(H S^{-}(a q)\ \leftrightharpoons\ H^{+}(a q)+S^{2-}(a q)\)

                                              \(K_{c}^{\prime \prime}=1.0 \times 10^{-19}\)

Calculate the equilibrium constant for the following reaction at the same temperature:

\(H_{2} S(a q)\ \leftrightharpoons\ 2 H^{+}(a q)+S^{2-}(a q)\)

ANSWER:

Step 1 of 2

Given equations:

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