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Draw all the resonance forms of the sigma complex for

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr ISBN: 9780321768414 33

Solution for problem 11P Chapter 17

Organic Chemistry | 8th Edition

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Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Organic Chemistry | 8th Edition

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Problem 11P

Problem 11P

Draw all the resonance forms of the sigma complex for nitration of bromobenzene at the ortho, meta, and para positions. Point out why the intermediate for meta substitution is less stable than the other two.

Step-by-Step Solution:
Step 1 of 3

Solution 11P

Nitration of bromobenzene -

In case of ortho and para attack of nitronium ion on bromobenzene there one more stable resonance structure; bromonium ion. Hence; meta substitution is less stable than the other two (ortho and para)

Step 2 of 3

Chapter 17, Problem 11P is Solved
Step 3 of 3

Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

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Draw all the resonance forms of the sigma complex for