Solution: Calorimetry (Section)Under constant-volume

Chapter , Problem 60E

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Problem 60E

Calorimetry (Section)

Under constant-volume conditions, the heat of combustion of benzoic acid (C6H5COOH) is 26.38 kJ/g. A 2.760-g sample of benzoic acid is burned in a bomb calorimeter. The temperature of the calorimeter increases from 21.60 to 29.93 °C. (a) What is the total heat capacity of the calorimeter? (b) A 1 440-g sample of a new organic substance is combusted in the same calorimeter. The temperature of the calorimeter increases from 22.14 to 27.09 °C. What is the heat of combustion per gram of the new substance? (c) Suppose that in changing samples, a portion of the water in the calorimeter were lost. In what way, if any, would this change the heat capacity of the calorimeter?

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