The following data were obtained for the reaction

Chapter 15, Problem 15.25

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The following data were obtained for the reaction 2ClO2(aq) 1 2OH2(aq) 88n ClO3 2(aq) 1 ClO2 2(aq) 1 H2O(l) where Rate 5 2 d3ClO2 4 dt [ClO2]0 (mol/L) [OH2]0 (mol/L) Initial Rate (mol L21 s21) 0.0500 0.100 5.75 3 1022 0.100 0.100 2.30 3 1021 0.100 0.0500 1.15 3 1021 a. Determine the rate law and the value of the rate constant. b. What would be the initial rate for an experiment with [ClO2]0 5 0.175 mol/L and [OH2]0 5 0.0844 mol/L?

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