Answer: Sulfuryl chloride undergoes first-order

Chapter 15, Problem 15.51

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Sulfuryl chloride undergoes first-order decomposition at 320.8C with a half-life of 8.75 h. SO2Cl2 1g2 h SO2 1g2 1 Cl2 1g2 What is the value of the rate constant, k, in s21? If the initial pressure of SO2Cl2 is 791 torr and the decomposition occurs in a 1.25-L container, how many molecules of SO2Cl2 remain after 12.5 h?

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