Answer: The decomposition of NH3 to N2 and H2 was studied

Chapter 15, Problem 15.94

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The decomposition of NH3 to N2 and H2 was studied on two surfaces: Surface Ea (kJ/mol) W 163 Os 197 Without a catalyst, the activation energy is 335 kJ/mol. a. Which surface is the better heterogeneous catalyst for the decomposition of NH3? Why? b. How many times faster is the reaction at 298 K on the W surface compared with the reaction with no catalyst present? Assume that the frequency factor A is the same for each reaction. c. The decomposition reaction on the two surfaces obeys a rate law of the form Rate 5 k 3NH3 4 3H2 4 How can you explain the inverse dependence of the rate on the H2 concentration?

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