Consider the following reaction: H2O1g2 1 Cl2O1g2m2HOCl1g2 K298 5 0.090 For Cl2O(g), DGf
Chapter 17, Problem 17.114(choose chapter or problem)
Consider the following reaction: H2O1g2 1 Cl2O1g2m2HOCl1g2 K298 5 0.090 For Cl2O(g), DGf 5 97.9 kJ/mol DHf 5 80.3 kJ/mol S 5 266.1 J/K # mol a. Calculate DG8 for the reaction using the equation DG8 5 2RT ln(K). b. Use bond energy values (Table 8.4) to estimate DH8 for the reaction. c. Use the results from parts a and b to estimate DS8 for the reaction. d. Estimate DH8f and S8 for HOCl(g). e. Estimate the value of K at 500. K. f. Calculate DG at 258C when PH2O 5 18 torr, PCl2O 5 2.0 torr, and PHOCl 5 0.10 torr.
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