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The dehydrogenation of butane to trans-but-2-ene has H = +116 kJ>mol (+27.6 kcal> mol)

Chapter 7, Problem PROBLEM 7-36

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QUESTION:

The dehydrogenation of butane to trans-but-2-ene has \(\Delta H^{\circ}=+116\ kJ/mol\ (+27.6\ kcal/mol)\) and \(\Delta S^{\circ}=+117\ J/kelvin-mol\ (+28.0\ cal/kelvin-mol)\).

(a) Compute the value of \(\Delta G^{\circ}\) for dehydrogenation at room temperature (\(25^{\circ}C\ \text{or}\ 298^{\circ}K\)). Is dehydrogenation favored or disfavored?

(b) Compute the value of \(\Delta G\) for dehydrogenation at \(1000^{\circ}C\), assuming that \(\Delta S\) and \(\Delta H\) are constant. Is dehydrogenation favored or disfavored?

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QUESTION:

The dehydrogenation of butane to trans-but-2-ene has \(\Delta H^{\circ}=+116\ kJ/mol\ (+27.6\ kcal/mol)\) and \(\Delta S^{\circ}=+117\ J/kelvin-mol\ (+28.0\ cal/kelvin-mol)\).

(a) Compute the value of \(\Delta G^{\circ}\) for dehydrogenation at room temperature (\(25^{\circ}C\ \text{or}\ 298^{\circ}K\)). Is dehydrogenation favored or disfavored?

(b) Compute the value of \(\Delta G\) for dehydrogenation at \(1000^{\circ}C\), assuming that \(\Delta S\) and \(\Delta H\) are constant. Is dehydrogenation favored or disfavored?

ANSWER:

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