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Organic Chemistry | 9th Edition | ISBN: 9780321971371 | Authors: Leroy G. Wade, Jan W. Simek
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Predict the masses and the structures of the most abundant fragments observed in the

Chapter 12, Problem 12-17

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QUESTION:

Predict the masses and the structures of the most abundant fragments observed in the mass spectra of the following compounds. (a) 2-methylpentane (b) 3-methylhex-2-ene (c) 4-methylpentan-2-ol (d) 2-methyl-1-phenylpropane (e) cyclohexyl isopropyl ether [cyclohexylOCH(CH3)2] (f) CH3CH2CH2NHC(CH3)3 tert@butyl propyl amine (g) C CH3 O acetophenone (g) *(h) 3-bromo-2-methylpentane

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QUESTION:

Predict the masses and the structures of the most abundant fragments observed in the mass spectra of the following compounds. (a) 2-methylpentane (b) 3-methylhex-2-ene (c) 4-methylpentan-2-ol (d) 2-methyl-1-phenylpropane (e) cyclohexyl isopropyl ether [cyclohexylOCH(CH3)2] (f) CH3CH2CH2NHC(CH3)3 tert@butyl propyl amine (g) C CH3 O acetophenone (g) *(h) 3-bromo-2-methylpentane

ANSWER:

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(a)

The mass and structure for the most observed fragments of 2-methylpentane are given as:

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