Zinc(lI) and the ligand L form a 1: 1 complex that absorhs strongly at 600 nm.As long as

Chapter 13, Problem 13-10

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Zinc(lI) and the ligand L form a 1: 1 complex that absorhs strongly at 600 nm.As long as the molar concentration of L exceeds that of zinc(II) by a factor of 5,the ahsorbance depends only on the cation concentration. Neither zinc(II) nor Lahsorhs at 600 nm. A solution that is 1.59 X 10' M in zinc(II) and 1.00 X 10 JM in L has an absorhance of 0.352 in a I.OO-cmcell at 600 nm. Calculate(a) the percent transmittance of this solution.(b) the percent transmittance of this solution in a 2.50-cm ccll,(c) the molar absorptivity of the complex.

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