Cyclohexanone exhibits its strongest IR absorption band at 5.86I-'m, and at
Chapter 17, Problem 17-1(choose chapter or problem)
Cyclohexanone exhibits its strongest IR absorption band at 5.86I-'m, and at thiswavelength there is a linear relationship between absorbance and concentration.(a) Identify the part of the molecule responsible for the absorbance at thiswavclength.(b) Suggest a solvent that would be suitable for a quantitative analysis of cyclohexanoneat this wavelength.(c) A solution of cyclohexanone (4.0 mg/mL) in the solvent selected in part(b) exhibits a blank-corrected absorbance of 0.800 in a cell with a path lengthof 0.025 mm. What is the detection limit for this compound under theseconditions if the noise associated with the spectrum of the solvent is 0.001absorbance units'!
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