Quinone undergoes a reversible reduction at a voltammetric working electrode.The

Chapter 25, Problem 25-10

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Quinone undergoes a reversible reduction at a voltammetric working electrode.The reaction is (a) Assume that the diffusion coefficient for quinone and hydroquinone areapproximately the same and calculate the approximate half-wave potential(versus SCE) for the reduction of hydroquinone at an ROE from a solutionbuffered to a pH of 7.0.(b) Repeat the calculation in (a) for a solution buffered to a pH of 5.G.

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