1 In experiment 1, a cyclic voltammogram at an HMOE was obtained'fUlm a0.167-mM solution

Chapter 25, Problem 25-11

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1 In experiment 1, a cyclic voltammogram at an HMOE was obtained'fUlm a0.167-mM solution of Pb2+ at a scan rate of 2.5 Vis. In experiment 2, a secondCV is to be obtained from a 4.38-mM solution of Cd 2+using the same HMOE.What must the scan rate be in expcriment 2 to record the same peak currentin both experiments if the diffusion coefficients of Cd" and Pb'+ are 0.72 X105 cm' s" and 0.98 cm' s", respectively. Assume that the reductions of bothcations are reversible at the HMOE.

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