Suppose 4.00 mol of an ideal gas undergoes a reversible isothermal expansion from volume V1 to volume V2 2.00V1 at temperature T 400 K. Find (a) the work done by the gas and (b) the entropy change of the gas. (c) If the expansion is reversible and adiabatic instead of isothermal, what is the entropy change of the gas?
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Textbook Solutions for Fundamentals of Physics, Volume 2 (Chapters 21 - 44)
Question
Expand 1.00 mol of an monatomic gas initially at 5.00 kPa and 600 K from initial volume Vi 1.00 m3 to final volume Vf 2.00 m3 .At any instant during the expansion, the pressure p and volume V of the gas are related by p 5.00 exp[(Vi V)/a], with p in kilopascals, Vi and V in cubic meters, and a 1.00 m3 . What are the final (a) pressure and (b) temperature of the gas? (c) How much work is done by the gas during the expansion? (d) What is S for the expansion? (Hint: Use two simple reversible processes to find S.)
Solution
The first step in solving 20 problem number 20 trying to solve the problem we have to refer to the textbook question: Expand 1.00 mol of an monatomic gas initially at 5.00 kPa and 600 K from initial volume Vi 1.00 m3 to final volume Vf 2.00 m3 .At any instant during the expansion, the pressure p and volume V of the gas are related by p 5.00 exp[(Vi V)/a], with p in kilopascals, Vi and V in cubic meters, and a 1.00 m3 . What are the final (a) pressure and (b) temperature of the gas? (c) How much work is done by the gas during the expansion? (d) What is S for the expansion? (Hint: Use two simple reversible processes to find S.)
From the textbook chapter Entropy and the Second Law of Thermodynamics you will find a few key concepts needed to solve this.
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