Two liquids, A and B, show partial miscibility below 52.4C. The critical concentration
Chapter 6, Problem 6.17(b)(choose chapter or problem)
Two liquids, A and B, show partial miscibility below 52.4C. The critical concentration at the upper critical temperature is x = 0.459, where x is the mole fraction of A. At 40.0C the two solutions in equilibrium have x = 0.22 and x = 0.60, respectively, and at 42.5C the mole fractions are 0.24 and 0.48. Sketch the phase diagram. Describe the phase changes that occur when B is added to a fixed amount of A at (a) 48C, (b) 52.4C.
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