- Chapter 1: THE PROPERTIES OF GASES
- Chapter 10: Atomic structure and atomic spectra
- Chapter 11: Molecular structure
- Chapter 12: Molecular symmetry
- Chapter 13: Molecular spectroscopy 1: rotational and vibrational spectra
- Chapter 14: Molecular spectroscopy 2: electronic transitions
- Chapter 15: Molecular spectroscopy 3: magnetic resonance
- Chapter 16: Statistical thermodynamics 1: the concepts
- Chapter 17: Statistical thermodynamics 2: applications
- Chapter 18: Molecular interactions
- Chapter 19: Materials 1: macromolecules and aggregates
- Chapter 2: The First Law
- Chapter 20: Materials 2: the solid state
- Chapter 21: Molecules in motion
- Chapter 22: The rates of chemical reactions
- Chapter 23: The kinetics of complex reactions
- Chapter 24: Molecular reaction dynamics
- Chapter 25: Processes at solid surfaces
- Chapter 3: The Second Law
- Chapter 4: Physical transformations of pure substances
- Chapter 5: Simple mixtures
- Chapter 6: Phase diagrams
- Chapter 7: Chemical equilibrium
- Chapter 8: Quantum theory: introduction and principles
- Chapter 9: Quantum theory: techniques and applications
Physical Chemistry 8th Edition - Solutions by Chapter
Full solutions for Physical Chemistry | 8th Edition
A high-energy molecular orbital resulting from the destructive interference between atomic orbitals.
A unit of pressure equal to 760 torr; 1 atm = 101.325 kPa. (Section 10.2) atom The smallest representative particle of an element. (Sections 1.1 and 2.1)
A class of colored compounds that are formed via azo coupling.
An instrument that measures atmospheric pressure. (5.2)
beta (b) anomer
The cyclic hemiacetal of an aldose, in which the hydroxyl group at the anomeric position is cis to the CH2OH group.
A low-energy molecular orbital resulting from the constructive interference between atomic orbitals.
concentration of a solution.
The amount of solute present in a given quantity of solvent or solution. (4.5)
A spectrum that contains radiation distributed over all wavelengths. (Section 6.3)
A method of problem solving in which units are carried through all calculations. Dimensional analysis ensures that the final answer of a calculation has the desired units. (Section 1.6)
An element that forms two bonds, such as oxygen.
The number of full cycles of a wave that pass a given point in a second, and reported in hertz (Hz), which has the units s21
The quantity of heat required to raise the temperature of a sample of matter by 1 °C (or 1 K). (Section 5.5)
Ionization potential (IP)
The minimum energy required to remove an electron from an atom or molecule to a distance where there is no electrostatic interaction between the resulting ion and electron.
A compound containing two carbon-carbon p bonds that are separated by two or more s bonds.
One that occurs at constant temperature. (Section 19.1)
A spherical arrangement of organic molecules in water solution clustered so that their hydrophobic parts are buried inside the sphere and their hydrophilic parts are on the surface of the sphere and in contact with water
In atomic and molecular orbitals, a location where the value of y is zero.
the number of degrees through which a compound rotates the plane of polarized light
Part per million (ppm)
Units used on NMR spectra to record chemical shift relative to the TMS standard.
Z (Section 5.2C)
From the German, zusammen, meaning opposite. Specifi es that groups of higher priority on the carbons of a double bond are on the same side
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