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Mole Fractions, Partial Pressures, and Total Pressure Calculation
Chapter 1, Problem 1.18(b)(choose chapter or problem)
A vessel of volume \(22.4\mathrm{\ dm}^3\) contains \(1.5\mathrm{\ mol}\mathrm{\ H}_2\) and \(2.5\mathrm{\ mol}\mathrm{\ N}_2\) at \(273.15\mathrm{\ K}\). Calculate (a) the mole fractions of each component, (b) their partial pressures, and (c) their total pressure.
Questions & Answers
QUESTION:
A vessel of volume \(22.4\mathrm{\ dm}^3\) contains \(1.5\mathrm{\ mol}\mathrm{\ H}_2\) and \(2.5\mathrm{\ mol}\mathrm{\ N}_2\) at \(273.15\mathrm{\ K}\). Calculate (a) the mole fractions of each component, (b) their partial pressures, and (c) their total pressure.
ANSWER:Step 1 of 3
a)
The mole fraction of any component in a solution is the number of moles of the component divided by the total number of moles making up a solution. It is denoted by “X”.
\(\begin{aligned} \text { Mole fraction }(X) & =\frac{\text { Moles of component }}{\text { Total number of moles making up the solution }} \\ X_{\text {Soluie }}+X_{\text {Solvent }} & =1 \end{aligned}\)
From the given,
Moles of hydrogen = 1.5 mol
Moles of nitrogen = 2.5 mol
Let’s calculate the mole fraction of hydrogen;
\(\begin{aligned} X_{H_{2}} & =\frac{\text { Moles of hydrogen }}{\text { Total moles of solution }} \\ & =\frac{1.5 \mathrm{~mol}}{1.5 \mathrm{~mol}+2.5 \mathrm{~mol}}=0.375 \end{aligned}\)
Hence, the mole fraction of hydrogen is 0.375.
Let’s calculate the mole fraction of nitrogen;
\(\begin{array}{l}\text{Mole fraction of Nitrogen }\left(X_{N_2}\right)+\text{ Mole fraction of Nitrogen }\left(X_{H_2}\right)=1\\ \text{Mole fraction of Nitrogen }\left(X_{N_2}\right)=1-\text{ Mole fraction of Hydrogen }\left(X_{H_2}\right)\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ =1-0.375=0.625\end{array}\)
Hence, the mole fraction of nitrogen is 0.625.
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Mole Fractions, Partial Pressures, and Total Pressure Calculation
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Explore the calculations for mole fractions, partial pressures, and total pressure in a 22.4 dm³ vessel with H? and N? at 273.15 K.