In formamide as solvent, poly( -benzyl-L-glutamate) is found by light scattering

Chapter 19, Problem 19.11

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In formamide as solvent, poly( -benzyl-L-glutamate) is found by light scattering experiments to have a radius of gyration proportional to M; in contrast, polystyrene in butanone has Rg proportional to M1/2. Present arguments to show that the first polymer is a rigid rod whereas the second is a random coil.

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