Discuss the limitations of the generality of the expression k = kakb[A]/(kb + ka[A]) for

Chapter 22, Problem 22.10

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Discuss the limitations of the generality of the expression k = kakb[A]/(kb + ka[A]) for the effective rate constant of a unimolecular reaction AP with the following mechanism: A + A5A* + A (ka, ka), A* P (kb). Suggest an experimental procedure that may either support or refute the mechanism.

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