The pKa of NH4 + is 9.25 at 25C. The rate constant at 25C for the reaction of NH4 + and

Chapter 22, Problem 22.13(a)

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The pKa of NH4 + is 9.25 at 25C. The rate constant at 25C for the reaction of NH4 + and OH to form aqueous NH3 is 4.0 1010 dm3 mol1 s1. Calculate the rate constant for proton transfer to NH3. What relaxation time would be observed if a temperature jump were applied to a solution of 0.15 mol dm3 NH3(aq) at 25C?

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