Use mathematical software or an electronic spreadsheet to examine the time dependence of
Chapter 22, Problem 22.12(choose chapter or problem)
Use mathematical software or an electronic spreadsheet to examine the time dependence of [I] in the reaction mechanism A IP (k1, k2). You may either integrate eqn 22.39 numerically (see Appendix 2) or use eqn 22.40 directly. In all the following calculations, use [A]0 = 1 mol dm3 and a time range of 0 to 5 s. (a) Plot [I] against t for k1 = 10 s1 and k2 = 1 s1. (b) Increase the ratio k2/k1 steadily by decreasing the value of k1 and examine the plot of [I] against t at each turn. What approximation about d[I]/dt becomes increasingly valid?
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