In the experiments described in 22.11 and 22.13 an inverse temperature dependence of the
Chapter 22, Problem 22.15(choose chapter or problem)
In the experiments described in Problems 22.11 and 22.13 an inverse temperature dependence of the reaction rate was observed, the overall rate of reaction at \(70^{\circ} \mathrm{C}\) being roughly one-third that at \(19^{\circ} \mathrm{C}\). Estimate the apparent activation energy and the activation energy of the rate-determining step given that the enthalpies of the two equilibria are both of the order of \(-14 \mathrm{~kJ} \mathrm{~mol}^{-1}\).
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