The second-order rate constants for the reaction of oxygen atoms with aromatic

Chapter 22, Problem 22.16

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The second-order rate constants for the reaction of oxygen atoms with aromatic hydrocarbons have been measured (R. Atkinson and J.N. Pitts, J. Phys. Chem. 79, 295 (1975)). In the reaction with benzene the rate constants are 1.44 107 dm3 mol1 s1 at 300.3 K, 3.03 107 dm3 mol1 s1 at 341.2 K, and 6.9 107 dm3 mol1 s1 at 392.2 K. Find the pre-exponential factor and activation energy of the reaction.

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