T. Gierczak, R.K. Talukdar, S.C. Herndon, G.L. Vaghjiani, and A.R. Ravishankara (J
Chapter 22, Problem 22.39(choose chapter or problem)
T. Gierczak, R.K. Talukdar, S.C. Herndon, G.L. Vaghjiani, and A.R. Ravishankara (J. Phys. Chem. A 101, 3125 (1997)) measured the rate constants for the bimolecular gas-phase reaction of methane with the hydroxyl radical in several isotopic variations. From their data, the following Arrhenius parameters can be obtained: A/(dm3 mol1 s1) Ea/(kJ mol1) CH4 + OHCH3 + H2O 1.13 109 14.1 CD4 + OHCD3 + DOH 6.0 108 17.5 CH4 + ODCH3 + DOH 1.01 109 13.6 Compute the rate constants at 298 K, and interpret the kinetic isotope effects.
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