A balloonist is preparing to make a trip in a

Chapter 5, Problem 60P

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QUESTION:

A balloonist is preparing to make a trip in a helium-filled balloon. The trip begins in early morning at a temperature of \(15^{\circ} \mathrm{C}\). By midafternoon, the temperature has increased to \(30^{\circ} \mathrm{C}\). Assuming the pressure remains constant at 1.00 atm, for each mole of helium, calculate:

The initial and final volumes

The change in internal energy,  E [Hint: Helium behaves like an ideal gas, so \(E=\frac{3}{2} n R T\).Be sure the units of R are consistent with those of E.]

The work (w) done by the helium (in J)

The heat (q) transferred (in J)

H for the process (in J)

Explain the relationship between the answers to (d) and (e).

Equation Transcription:

15°C

30°C

E

Text Transcription:

15°C

30°C

Delta E

E=3/2nRT

Questions & Answers

QUESTION:

A balloonist is preparing to make a trip in a helium-filled balloon. The trip begins in early morning at a temperature of \(15^{\circ} \mathrm{C}\). By midafternoon, the temperature has increased to \(30^{\circ} \mathrm{C}\). Assuming the pressure remains constant at 1.00 atm, for each mole of helium, calculate:

The initial and final volumes

The change in internal energy,  E [Hint: Helium behaves like an ideal gas, so \(E=\frac{3}{2} n R T\).Be sure the units of R are consistent with those of E.]

The work (w) done by the helium (in J)

The heat (q) transferred (in J)

H for the process (in J)

Explain the relationship between the answers to (d) and (e).

Equation Transcription:

15°C

30°C

E

Text Transcription:

15°C

30°C

Delta E

E=3/2nRT

ANSWER:

Solution 60P:

Step 1: (a)

Here, we are going to calculate the initial and final volume of the gas.

For initial volume (Vinitial)

Given that,

Pressure, P =1.0 atm

Gas constant, R =0.0821 atm.L.mol-1K-1

Moles, n=1.0 mol

Temperature, T =15°C =273.15 +15 =288.15 K

We know from the ideal gas equation,

=

        =

        =23.657 L

Thus, the initial volume of He gas is 23.66 L.


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